By W. Hüttner (auth.), W. Hüttner (eds.)
This is subvolume C of the Landolt-Börnstein quantity II/29 "Molecular Constants more often than not from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy", that is deliberate to seem as a sequence A, B, C and D1 and D2 for the diamagnetic, and E for the paramagnetic linear and polyatomic species, respectively. Like within the previous volumes II/19 and II/24, that have seemed in 1992 and 1999, the diamagnetic ingredients are prepared within the demeanour instructed by means of Hill ("Hill's system", 1900), which means a virtually strict alphabetical order; info are given within the basic creation at the following pages. The ionic species are incorporated within the alphabetical association of the impartial ones in each one desk. within the preface to the former quantity II/24 we had famous: it's a bit of stunning that the fashion of decreasing spectroscopic actions in universities and different learn institutes has now not resulted in a decrease construction cost of pertinent molecular literature facts over the last say ten years. it sounds as if the other is correct. The variety of reviews of Van der Waals complexes remains to be expanding, and of course additionally their complexity. equally, the "normal" molecules studied less than high-resolution stipulations turned extra advanced and versatile, and fascinating results like internal hydrogen bonding were investigated. The variety of figures used to demonstrate the molecular conformational constructions is, hence, additionally better than within the foregoing volumes.
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X = Xȣ í X0. q3444 is a coefficient of the matrix element υ3υ4 Jkl3l4 H υ3 − 1,υ4 + 3, J , k ± 2, l3 ± 1, l4 ± 1 = ( q3444 + q3444 J J ( J + 1) )( J ( J + 1) − k (k ± 1) ) ( J ( J + 1) − (k ± 1)(k ± 2) ) 1/ 2 Quantum State 11 1/ 2 . 136788 010033 Fixed at the values of 010031. 691686(21) Other parameters fixed at the values of 000020. 00094(20) Other parameters fixed at the values of 000031. : J. Mol. Spectrosc. 234 (2005) 122. : J. Mol. Spectrosc. 238 (2006) 135. : J. Phys. Chem. A 105 (2001) 484.
J. Chem. Phys. 114 (2001) 3968. : J. Mol. Spectrosc. 214 (2002) 202. : 156387-58-5 H H Si H Ar H A, E, and F denote the spin modifications of SiH4. u denotes the upper component of the Ɛ-doublet and l the lower component. Ȉ corresponds to K = 0, Ȇ to ȍ = 1, etc. Ȟs is the pseudodiatomic stretching frequency. : J. Mol. Spectrosc. 197 (1999) 232. : Chem. Phys. Lett. 335 (2001) 381. : Chem. Phys. Lett. 335 (2001) 381. : J. Chem. Phys. 114 (2001) 1242. : J. Chem. Phys. 114 (2001) 1242. : 423721-76-0 Remark: The index s denotes the symmetric component of the inversion tunneling splitting, a the antisymmetric component.
Phys. 57 (1972) 4207. : Chem. Phys. 23 (1977) 71. Aliev, M. , Hougen, J. : J. Mol. Spectrosc. 106 (1984) 110. : J. Mol. Spectrosc. 131 (1988) 77. , Merer, A. Phys. 98 (2000) 1597. : J. Mol. Spectrosc. 211 (2002) 1. : CODATA recommended values of the fundamental physical constants: 2006, in J. Phys. Chem. Ref. 6 (2008). 1007/978-3-540-47532-3_2 © Springer 2010 Lando lt -Bö rnst ein New Series II/29C Ref. p. 1 Defining equations The rotational spectrum of a molecule with internal rotation (torsion) is modified due to torsion-rotation interaction.